Solid State and Materials Chemistry
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ROBUST ANTIFERROMAGNETISM PREVENTING SUPERCONDUCTIVITY IN PRESSURIZED (BA 0.61 K 0.39)MN2BI2.

Figure 1: Electrical resistance as a function of temperature and pressure for Ba0.61K0.39Mn2Bi2.

 

(a) and (b) Temperature dependent resistance of Ba0.61K0.39Mn2Bi2 at different pressures. (c) Pressure dependence of resistance measured at different temperatures, displaying a dome-like feature centered at ~20–23 GPa. (d) and (e) Blown-up R-T curves at different pressures, showing no evidence of superconductivity.

 

BaMn2Bi2 possesses an iso-structure of iron pnictide superconductors and similar antiferromagnetic (AFM) ground state to that of cuprates, therefore, it receives much more attention on its properties and is expected to be the parent compound of a new family of superconductors. When doped with potassium (K), BaMn2Bi2 undergoes a transition from an AFM insulator to an AFM metal. Consequently, it is of great interest to suppress the AFM order in the K-doped BaMn2Bi2 with the aim of exploring the potential superconductivity.

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Contributors: Dachun GuXia DaiCongcong LeLiling SunQi WuBayrammurad SaparovJing GuoPeiwen Gao,Shan ZhangYazhou ZhouChao ZhangShifeng JinLun XiongRui LiYanchun LiXiaodong LiJing LiuAthena S SefatJiangping HuZhongxian Zhao

EMPLOYING LEAD THIOCYANATE ADDITIVE TO REDUCE THE HYSTERESIS AND BOOST THE FILL FACTOR OF PLANAR PEROVSKITE SOLAR CELLS.

Lead thiocyanate in the perovskite precursor can increase the grain size of a perovskite thin film and reduce the conductivity of the grain boundaries, leading to perovskite solar cells with reduced hysteresis and enhanced fill factor. A planar perovskite solar cell with grain boundary and interface passivation achieves a steady-state efficiency of 18.42%.

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Contributors:

Weijun KeChuanxiao XiaoChanglei WangBayrammurad SaparovHsin-Sheng DuanDewei Zhao,Zewen XiaoPhilip SchulzSteven P HarveyWeiqiang LiaoWeiwei MengYue YuAlexander J CimaroliChun-Sheng JiangKai ZhuMowafak Al-JassimGuojia FangDavid B MitziYanfa Yan